4.1. The Vapor-Compression Refrigeration Cycle
The vapor-compression refrigeration cycle has four components: evaporator, compressor, condenser, and expansion (or throttle) valve. The most widely used refrigeration cycle is the vapor-compression refrigeration cycle. In an ideal vapor-compression refrigeration cycle, the refrigerant enters the compressor as a slightly superheated vapor at a low pressure. It then leaves the compressor and enters the condenser as a vapor at some elevated pressure, where the refrigerant is condensed as heat is transferred to cooling water or to the surroundings. The refrigerant then leaves the condenser as a high-pressure liquid. The pressure of the liquid is decreased as it flows through the expansion valve, and as a result, some of the liquid flashes into cold vapor. The remaining liquid, now at a low pressure and temperature, is vaporized in the evaporator as heat is transferred from the refrigerated space. This vapor then reenters the compressor.

The refrigerant enters the compressor Vapor-compression refrigeration cycles specifically have two additional advantages. First, they exploit the large thermal energy required to change a liquid to a vapor so we can remove lots of heat out of our air-conditioned space. Second, the isothermal nature of the vaporization allows extraction of heat without raising the temperature of the working fluid to the temperature of whatever is being cooled. This is a benefit because the closer the working fluid temperature approaches that of the surroundings, the lower the rate of heat transfer. The isothermal process allows the fastest rate of heat transfer. The cycle operates at two pressures, Phigh and Plow, and the statepoints are determined by the cooling requirements and the properties of the working fluid. Most coolants are designed so that they have relatively high vapor pressures at typical application temperatures to avoid the need to maintain a significant vacuum in the refrigeration cycle.

The ideal vapor-compression cycle consists of four processes.

Ideal Vapor-Compression Refrigeration Cycle

Process Description
1-2 Isentropic compression
2-3 Constant pressure heat rejection in the condenser
3-4 Throttling in an expansion valve
4-1 Constant pressure heat addition in the evaporator


The P-h diagram is another convenient diagram often used to illustrate the refrigeration cycle.


The ordinary household refrigerator is a good example of the application of this cycle

Actual Vapor-Compression Refrigeration Cycle


4.2. Cascade refrigeration systems
Very low temperatures can be achieved by operating two or more vapor-compression systems in series, called cascading. The COP of a refrigeration system also increases as a result of cascading.


4.3. Multistage compression refrigeration systems



4.4. Multipurpose refrigeration systems
A refrigerator with a single compressor can provide refrigeration at several temperatures by throttling the refrigerant in stages


4.5. Liquefaction of gases
Another way of improving the performance of a vapor-compression refrigeration system is by using multistage compression with regenerative cooling. The vapor-compression refrigeration cycle can also be used to liquefy gases after some modifications.


4.6. Gas Refrigeration Systems
The power cycles can be used as refrigeration cycles by simply reversing them. Of these, the reversed Brayton cycle, which is also known as the gas refrigeration cycle, is used to cool aircraft and to obtain very low (cryogenic) temperatures after it is modified with regeneration. The work output of the turbine can be used to reduce the work input requirements to the compressor. Thus, the COP of a gas refrigeration cycle is


4.7. Absorption Refrigeration Systems
Another form of refrigeration that becomes economically attractive when there is a source of inexpensive heat energy at a temperature of 100 to 200°C is absorption refrigeration, where the refrigerant is absorbed by a transport medium and compressed in liquid form. The most widely used absorption refrigeration system is the ammonia-water system, where ammonia serves as the refrigerant and water as the transport medium. The work input to the pump is usually very small, and the COP of absorption refrigeration systems is defined as



4.8. Thermoelectric Refrigeration Systems
A refrigeration effect can also be achieved without using any moving parts by simply passing a small current through a closed circuit made up of two dissimilar materials. This effect is called the Peltier effect, and a refrigerator that works on this principle is called a thermoelectric refrigerator.

The thermoelectric device, like the conventional thermocouple, uses two dissimilar materials. There are two junctions between these two materials in a thermoelectric refrigerator. One is located in the refrigerated space and the other in ambient surroundings. When a potential difference is applied, as indicated, the temperature of the junction located in the refrigerated space will decrease and the temperature of the other junction will increase. Under steady-state operating conditions, heat will be transferred from the refrigerated space to the cold junction. The other junction will be at a temperature above the ambient, and heat will be transferred from the junction to the surroundings. A thermoelectric device can also be used to generate power by replacing the refrigerated space with a body that is at a temperature above the ambient.

4.9. Air conditioners

An air conditioner uses a material called a "working fluid" to transfer heat from inside of a room to the great outdoors. The working fluid is a material which transforms easily from a gas to a liquid and vice versa over a wide range of temperatures and pressures. This working fluid moves through the air conditioner's three main components, the compressor, the condenser, and the evaporator in a continuous cycle.


The working fluid enters the evaporator inside the room as a low-pressure liquid at approximately outside air temperature. (1) The evaporator is typically a snake-like pipe. The fluid immediately begins to evaporate and expands into a gas. In doing so, it uses its thermal energy to separate its molecules from one another and it becomes very cold. Heat flows from the room to this cold gas. The working fluid leaves the evaporator as a low-pressure gas a little below room temperature and heads off toward the compressor. (2) It enters the compressor as a low-pressure gas roughly at room temperature. The compressor squeezes the molecules of that gas closer together, increasing the gas's density and pressure. Since squeezing a gas involves physical work, the compressor transfers energy to the working fluid and that fluid becomes hotter. The working fluid leaves the compressor as a high-pressure gas well above outside air temperature. (3) The working fluid then enters the condenser on the outside, which is typically a snake-like pipe. Since the fluid is hotter than the surrounding air, heat flows out of the fluid and into the air. The fluid then begins to condense into a liquid and it gives up additional thermal energy as it condenses. This additional thermal energy also flows as heat into the outside air. The working fluid leaves the condenser as a high-pressure liquid at roughly outside air temperature. (4) It then flows through a narrowing in the pipe into the evaporator. When the fluid goes through the narrowing in the pipe, it's pressure drops and it enters the evaporator as a low-pressure liquid. The cycle repeats. Overall, heat is been extracted from the room and delivered to the outside air. The compressor consumes electric energy during this process and that energy also becomes thermal energy in the outside air. The maximum coefficient of such an air conditioner is Emax = Troom / (Toutside – Troom).
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